domingo, 29 de janeiro de 2012

Chemistry






What is Chemistry?


Chemistry is the study of matter and energy and the interactions between them. This is also the definition for physics. Chemistry and physics are specializations of physical science. Chemistry tends to focus on the properties of substances and the interactions between different types of matter, particularly reactions that involve electrons. 

 
What do Scientiscs think is made of chemistry?


Everything you hear, see, smell, taste, and touch involves chemistry and chemicals (matter). In more formal terms chemistry is the study of matter and the changes it can undergo. Matter is anything that has mass and occupies space. Which is to say, anything you can touch or hold. Common usage might have us believe that ‘chemicals’ are just those substances in laboratories or something that is not a natural substance. Far from it, chemists believe that everything is made of chemicals. Chemistry is not limited to beakers and laboratories. It is all around us, and the better we know chemistry, the better we know our world.


States of Matter





Gases, liquids and solids are all made up of microscopic particles, but the behaviors of these particles differ in the three phases. The following figure illustrates the microscopic differences.


Microscopic view of a gas
Microscopic view of a liquid.
Microscopic view of a solid.
Microscopic view of a gas.
Microscopic view of a liquid.
Microscopic view of a solid.


Note that:

  • Particles in a:
    • gas are well separated with no regular arrangement.
    • liquid are close together with no regular arrangement.
    • solid are tightly packed, usually in a regular pattern.
  • Particles in a:
    • gas vibrate and move freely at high speeds.
    • liquid vibrate, move about, and slide past each other.
    • solid vibrate  but generally do not move from place to place.

The following table summarizes properties of gases, liquids, and solids and identifies the microscopic behavior responsible for each property.










Some Characteristics of Gases, Liquids and Solids and the Microscopic Explanation for the Behavior

gas
liquid
solid
assumes the shape and volume of its container
particles can move past one another
assumes the shape of the part of the container which it occupies
particles can move/slide past one another
retains a fixed volume and shape
rigid - particles locked into place
compressible
lots of free space between particles
not easily compressible
little free space between particles
not easily compressible
little free space between particles
flows easily
particles can move past one another
flows easily
particles can move/slide past one another
does not flow easily
rigid - particles cannot move/slide past one another



The three states of Matter Diagram

Solutions 



Homogeneuos vs Heterogeneous


Solutions are groups of molecules that are mixed up in a completely even distribution.This means that they are homogenous system.Other types of mixtures can have a little higher concentration on one side of the liquid when compared to the other side. So, they are heterogenous.


Can Anything Be In Solution?


Solutions can be solids dissolved in liquids. They could also be gases dissolved in liquids. There can also be gases in other gases and liquids in liquids. If you mix things up and they stay at an even distribution, it is a solution.
  A simple solution is basically two substances that are going to be combined. One of them is called the solute. A solute is the substance to be dissolved . The other is a solvent. The one that is going to  do the dissolving. 


Can Anything Change Solutions?


All sorts of things  can change the concentrations of substances in solution.
 Solubility is the ability of the solvent  to dissolve the solute .  Some things like temperature, pressure and structure  of substance can modify it's solubility .
 Sugar dissolves easily in water; oil does not. Water has a low solubility when it comes to oil. 







SATURATED SOLUTIONS


Only a finite amount of solid will dissolve in a liquid and this is dependent on the solid  and the temperature. When no more solid will dissolve the solution is saturated, but generally more will dissolve in hot than in cold liquid and it will dissolve faster if you stir the solution.
So if a saturated solution of sugar is made using hot water, as it cools some of the sugar comes out of solution and reforms making crystals. This principle is used to grow crystals. Crystals can also, of course, be made by leaving a salt or sugar solution and allowing the water to evaporate leaving salt or sugar crystals behind.





People often confuse melting and dissolving and this may be a point of discussion. Melting requires heat and dissolving requires a solvent. In making a jelly both are happening when it is added to hot water.











What is a mixture?

Mixing materials together forms a mixture where two or more substances are physically but not chemically combined and can be separated again by physical methods such as sieving, filtering, evaporating etc. This means that the change can be reversed. A new material is not formed as it is in a chemical reaction. Mixtures can be made up of 


  • solid in solid (muesli)
  • gas in solid (pumice stone)
  • solid in gas (smoke)
  • gas in gas (air – mostly made up of nitrogen and oxygen)
  • liquid in gas (clouds, mist, aerosol)
  • gas in liquid (oxygen in water)
  • liquid in liquid (emulsion – milk)
  • insoluble solid in liquid (suspension – muddy water)
  • soluble solid in liquid (solution – salt water). 
A mixture is an impure substance that can be separated into pure substance by physical means. eg. dirty water can be purified by filtration.
 There are many different methods of separating mixtures. Each method relies on differences in the physical properties of the components of the mixture.






Methods of Physical Separation
Method of separationUsed to separateBasis - differences inExample
FiltrationAn insoluble solid from a liquidSolubilityMuddy water
DecantingAn insoluble solid from a liquidSolubility and densityWater and sand
CentrifugingAn insoluble solid from a liquidSolubility and densityBlood cells from plasma
EvaporatingA soluble solid from a liquidBoiling pointSalt from sea water
DistillationA liquid from a soluble solidBoiling pointWater from sea water
Fractional distillation
Miscible liquids
(liquids that can be mixed together as one)
Boiling pointAlcohol from water
Separating funnelImmiscible liquids (liquids that do not mix)Density and miscibilityOil and water
Paper chromatographySoluble substancesRetention rates on paperFood coloring
CrystallizationSoluble substancesSolublilityDifferent salts


Filtration                                                                  Distillation                                                         



What is a pure substance?

 pure substance is a substance that cannot be separated by physical means. eg. filtration, evaporation, distillation or chromatography.





  • What is pure Water?

What Is Pure Water



Pure water is water which has been purified naturally from its contaminants. The contaminants can be in the form of bacteria and other substances as of salt, calcium, magnesium and so on. Pure water has a pH value of 7 or close to 7.Normally, pure water is odorless and tasteless, because it does not contain any contaminant.






Acids and Alkalis




Acid: A solution that has an excess of H+ ions. It comes from the Latin word acidus that means "sharp" or "sour".

Some acids are too dangerous to taste and they can be corrosive!



This group of substances include:
- vinegar
- fruit juices
- hydrochloric acid ( stomach acid)- ascorbic acid (vitamin C)
- acid rain (sulphuric and nitric acid)

This substances turns indicators (litmus) into red



Stomach acid reflux


Alkali: A solution that has an excess of OH- ions. It comes from arabic word ´al kali´that means ashes used by Arabic scientist mixed with water and animal fats to make the first soup.Alkali describe a group of substances that feel soapy.However, many alkalis are too dangerous to feel.

This group include,for example:

- Soap

- Toothpaste
- Oven cleaner


This substances turn indicator blue.














Substances that are neither acids or alkalis are called neutral.Pure water, sat and sugar are all neutral. Neutral substances do not affect indicators at all.

                                 




What is a chemical indicator?



A chemical indicator is a substance that changes color in the presence of an acid and an alkali
Chemical indicators are a safer way to determine if a chemical substance is acidic or basic.
Chemical indicatorColor in acidColor in base
Litmus paperPink /RedBlue
PhenolphthaleinColorlessPink/ violet
Bromothymol blueYellowBlue


                
 Chemical indicators are commonly used to test the acidic. basic nature of soils.
They are also used to test the acidic basic conditions of water in swimming pools and fish tanks.

What is a universal indicator?



A universal indicator is a solution which undergoes several color changes over a wide range of pH's. The color is used to "indicate" pH directly. Universal indicators are usually mixtures of several indicators.



What is the pH scale?

The pH scale is a measure of how acidic or basic a chemical substance is.






  • A pH of 7 is netural
  • A pH less than 7 is acidic 
  • A pH greater than 7 is basic
Strengthstrong acidsweak acidsneutralweak basesstrong bases
pH0-23-678-1011-14
ExamplesCar acid batteriesLemon juiceWaterToothpasteOven cleaner